Contributed by:
kevin
Mon, Jan 24, 2022 07:08 AM UTC
An acid is a substance that donates protons (in the Brønsted-Lowry definition) or accepts a pair of valence electrons to form a bond (in the Lewis definition). A base is a substance that can accept protons or donate a pair of valence electrons to form a bond. Bases can be thought of as the chemical opposite of acids.
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Chemistry 19.1 Slide 1 of 35
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19.1 Acid-Base Theories Bracken Cave, near San Antonio, Texas, is home to twenty to forty million bats. Visitors to the cave must protect themselves from the dangerous levels of ammonia in the cave. Ammonia is a byproduct of the bats’ urine. You will learn why ammonia is considered a base. Slide 2 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Properties of Acids and Bases Properties of Acids and Bases What are the properties of acids and bases? Slide 3 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Properties of Acids and Bases Acids taste sour, will change the color of an acid- base indicator, and can be strong or weak electrolytes in aqueous solution. Slide 4 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Properties of Acids and Bases Citrus fruits contain citric acid. Tea contains tannic acid. Slide 5 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Properties of Acids and Bases Bases taste bitter, feel slippery, will change the color of an acid-base indicator, and can be strong or weak electrolytes in aqueous solution. Slide 6 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Properties of Acids and Bases Antacids use bases to neutralize excess stomach acid. The base calcium hydroxide is a component of mortar. Slide 7 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Arrhenius Acids and Bases How did Arrhenius define an acid and a base? Slide 8 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Arrhenius said that acids are hydrogen- containing compounds that ionize to yield hydrogen ions (H+) in aqueous solution. He also said that bases are compounds that ionize to yield hydroxide ions (OH–) in aqueous solution. Slide 9 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Hydrochloric Acid Slide 10 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Arrhenius Acids • Acids that contain one ionizable hydrogen, such as nitric acid (HNO3), are called monoprotic acids. • Acids that contain two ionizable hydrogens, such as sulfuric acid (H2SO4), are called diprotic acids. • Acids that contain three ionizable hydrogens, such as phosphoric acid (H3PO4) are called triprotic acids. Slide 11 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Slide 12 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Arrhenius Bases Hydroxide ions are one of the products of the dissolution of an alkali metal in water. Slide 13 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Slide 14 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Arrhenius Acids and Bases Milk of magnesia is a base used as an antacid. Slide 15 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Brønsted-Lowry Acids and Bases Brønsted-Lowry Acids and Bases What distinguishes an acid from a base in the Brønsted-Lowry theory? Slide 16 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Brønsted-Lowry Acids and Bases The Brønsted-Lowry theory defines an acid as a hydrogen-ion donor, and a base as a hydrogen-ion acceptor. Slide 17 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Brønsted-Lowry Acids and Bases Why Ammonia is a Base Slide 18 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Brønsted-Lowry Acids and Bases Conjugate Acids and Bases • A conjugate acid is the particle formed when a base gains a hydrogen ion. • A conjugate base is the particle that remains when an acid has donated a hydrogen ion. Slide 19 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Brønsted-Lowry Acids and Bases • A conjugate acid-base pair consists of two substances related by the loss or gain of a single hydrogen ion. • A substance that can act as both an acid and a base is said to be amphoteric. Slide 20 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Brønsted-Lowry Acids and Bases Slide 21 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Brønsted-Lowry Acids and Bases A water molecule that gains a hydrogen ion becomes a positively charged hydronium ion (H3O+). Slide 22 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Lewis Acids and Bases Lewis Acids and Bases How did Lewis define an acid and a base? Slide 23 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Lewis Acids and Bases Lewis proposed that an acid accepts a pair of electrons during a reaction, while a base donates a pair of electrons. Slide 24 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Lewis Acids and Bases • A Lewis acid is a substance that can accept a pair of electrons to form a covalent bond. • A Lewis base is a substance that can donate a pair of electrons to form a covalent bond. Slide 25 of 35 © Copyright Pearson Prentice Hall
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Acid-Base Theories > Lewis Acids and Bases Animation 25 Compare the three important definitions of acids and bases. Slide 26 of 35 © Copyright Pearson Prentice Hall
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19.1 Acid-Base Theories > Lewis Acids and Bases Slide 27 of 35 © Copyright Pearson Prentice Hall
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Acid-Base Theories > Slide 28 of 35 © Copyright Pearson Prentice Hall
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Acid-Base Theories > Slide 29 of 35 © Copyright Pearson Prentice Hall
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Acid-Base Theories > Slide 30 of 35 © Copyright Pearson Prentice Hall
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Practice Problems for Conceptual Problem 19.1 Problem Solving 19.1 Solve Problem 1 with the help of an interactive guided tutorial. Slide 31 of 35 © Copyright Pearson Prentice Hall
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19.1 Section Quiz. Assess students’ understanding of the concepts in Section 19.1. Continue to: Launch: -or- Section Quiz Slide 32 of 35 © Copyright Pearson Prentice Hall
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19.1 Section Quiz. 1. Which of the following is NOT a characteristic of acids? a. taste sour b. are electrolytes c. feel slippery d. affect the color of indicators Slide 33 of 35 © Copyright Pearson Prentice Hall
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19.1 Section Quiz. 2. Which compound is most likely to act as an Arrhenius acid? a. H2O b. NH3. c. NaOH. d. H2SO4. Slide 34 of 35 © Copyright Pearson Prentice Hall
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19.1 Section Quiz. 3. A Lewis acid is any substance that can accept a. a hydronium ion. b. a proton. c. hydrogen. d. a pair of electrons. Slide 35 of 35 © Copyright Pearson Prentice Hall